Corneliu Balan, Ralf Riedel
Sol-Gel Modelling Associated with the Rheology of Polymeric Precursors of Ceramic Materials
Appl. Rheol. 13:5 (2003) 251-258Abstract: A general constitutive relation describing the change of viscoelastic behavior during the liquid - solid (sol - gel) transition which takes place in preceramic polymers is derived on the basis of Jeffrey.s 3-constants model with time dependent viscosities and elasticity. It is postulated that the sol - gel - transition can be analyzed analogous to the solutions of the Avrami equation used for modeling crystallization processes. Two different polymer systems used as precursor for the production of ceramic materials are investigated here: i) a mixture based on polysiloxane, alumatrane and isopropanol; ii) a non-oxidic carbodiimide gel based on the reaction of chlorosilanes with bis(trimethylsilyl)carbodiimide. Continuous measurements of the dynamic moduli versus reaction time, as well as creep tests at constant shear stress, evidenced both qualitative similarities and quantitative differences associated with the sol - gel transition of the two polymer systems. The shear rate and viscosity dependence of reaction time in creep tests, respectively the evolution of Lissajous figures associated with oscillatory experiments, are found to be consistent with the numerical simulations of the proposed constitutive relation. © 2003 Applied Rheology.
-- full text PDF
available for subscribers --
-- open access PDF extractavailable for non-subscribers --
You have no password-free access to Applied Rheology Online. If you are a subscriber, enter login details below. For password-free access, we need your IP address. Sample manuscripts for free download can be found here ►
Forgotten your login details? Send an email with subject "AR login" to login@appliedrheology.org
Purchase this article for 20 € ? ►
Appl Rheol 13 (2003) issues:
© Applied Rheology 2018