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New controlled release systems produced by self-assembly of biopolymers and colloidal particles at fluid-fluid interfaces
The equilibrium aqueous solubility of a commercial carob flour was investigated by determining the percentage of soluble and insoluble components as a function of dissolution temperature. The cumulative polysaccharide yield was ca. 50% at 5 degrees C, increasing approximately as a linear function of temperature to ca. 90% at 85 degrees C. Overall molecular weight and intrinsic viscosity of the soluble polysaccharide were determined by size-exclusion chromatography. With increasing dissolution temperature, there was weak trend towards higher overall molecular weight and intrinsic viscosity: M-w from 1060 to 1150 kg/mol, and [eta] from 11.8 to 12.5 dl/g, between 5 and 65 degrees C, respectively. Broad, amorphous peaks were evident in the(e) wide-angle X-ray scattering profiles, indicating no role for polysaccharide melting.,The continuous increase of molecular weight and decrease of DSgal with dissolution temperature is interpreted as the result of thermodynamic partitioning based on a classical polymer-solvent fractionation, a mechanism that applies only for polysaccharide components with DSgal<0.35 within the accessible temperature range. (C) 2006 Elsevier Ltd. All rights reserved. [hide]
Scientific Board
Andreas Bausch
TU Munich, Germany ►
Peter Fischer
ETH Zurich, Switzerland ►
Anne-Marie Hermansson
SIK, Sweden ►
Martin Kroger
ETH Zurich, Germany/Switzerland ►
Erik van der Linden
Wageningen UR, The Netherlands ►
Niklas Loren
SIK, Sweden ►
Leonard Sagis
Wageningen UR, The Netherlands ►
Erich Windhab
ETH Zurich, Switzerland ►
Klaas-Jan Zuidam
Unilever, The Netherlands ►
Scientific Stuff
Manuela Duxenneuner
ETH Zurich, Switzerland ►
Sophia Fransson
SIK, Sweden ►
Nam-Phuong Humblet-Hua
Wageningen UR, The Netherlands ►
Joeska Husny
ETH Zurich, Australia/Switzerland ►
Orit Peleg
ETH Zurich, Israel/Switzerland ►
Cyrille Vezy
TU Munich, Germany ►
Varvara Mitropoulos
ETH Zurich, Switzerland ►
Associated Scientists
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SY Tee, AR Bausch, PA Janmey,
The mechanical cell
CURRENT BIOLOGY 19 (2009) R745 ►Selected conferences (co-)organized by project members
8th World Congress on Computational Mechanics WCCM8 2008
30 June - 5 July 2007, Venice, Italy ►13 May 2025
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