Nicolas Jullian, Frederic Leonardi, Bruno Grassl, Jean Peyrelasse, Christophe Derail
Rheological characterization and molecular modeling of poly(n-butyl acrylate)
Appl. Rheol. 20:3 (2010) 33685 (11 pages)Abstract: We propose an exhaustive experimental characterization of a series of poly(n-butyl acrylate) samples that were synthesized by controlled radical polymerization and have different molecular weights. We focus on the rheological behavior of these polymers and propose a model of their rheological behavior using a molecular model based on the reptation concept.We report the principal rheological parameters for these homopolymers and demonstrate good agreement between model predictions and experimental data. © 2010 Applied Rheology.
DOI 10.3933/ApplRheol-20-33685
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